Vapor pressure lab
Do not over tighten the valves! To insert the temperature probe first place the inlet adapter into the Claisen adapter. Rapid movement can break the gauge leading to a mercury spill. Freeman: New York,p.
Therefore, most of the vapor is at a different temperature than the liquid. Perform an error analysis to determine whether any differences are statistically significant. Decrease the pressure in the system and then close the pump valve. Start the mechanical pump.
Vapor pressure of a solution lab
Use a small clamp to hold the probe in a vertical position so that it does not touch the sides. To insert the temperature probe first place the inlet adapter into the Claisen adapter. Unscrew the blue retaining ring from the inlet adapter and slip the retaining ring and then the o-ring on to the probe. The McLeod gauge must be left under vacuum at all times for it to function properly. If the pressure is in the correct range, enter the pressure reading from the McLeod gauge as the second calibration point to finish the calibration. Figure 2. Under no circumstances is the valve to the pump be left open while the system is open to the atmosphere and the pump is running. The pressure reading displayed by LoggerPro should return to ambient pressure. Turn off the pump and open the pump valve on the manifold to vent the pump. Atkins, P.
For real gases, however, Z itself will decrease with increasing temperature, which should give some degree of curvature to the graph at high temperatures. Record the ambient pressure in mm Hg from the laboratory barometer and correct the pressure using the equation posted by the barometer.
Upon coming to laboratory check that the manifold, McLeod gauge and ballast bulb have already been assembled and make sure all valves on the manifold are closed.
Slowly open the valve to the pump and evacuate the system to the desired pressure take care that the sample does not start to boil and then close the valve.
Vapor pressure equation
Return the heating mantle to the flask and gently heat to boiling, as described above. When you are finished, close the pump valve and open the vent valve to return the system to ambient pressure the valve to the distillation apparatus should be open at this point. Under no circumstances is the valve to the pump be left open while the system is open to the atmosphere and the pump is running. Be sure to make all hose connections to the distillation apparatus before clamping it in place and do not forget to grease the ground glass joints with a small amount of high-vacuum silicone grease. Freeman: New York, , p. Figure 2. If we have data on the constant pressure heat capacity of both the vapor and the liquid over the temperature range of interest, we can evaluate the integral in Eqn. The pressure reading displayed by LoggerPro should return to ambient pressure. To insert the temperature probe first place the inlet adapter into the Claisen adapter. Do not over tighten the valves! Within a minute or two the pump should grow quiet as the air is removed from the line and ballast bulb; if it does not then there is a leak somewhere that must be sealed most likely at the septum stopper. Repeat until ambient pressure is reached. Do NOT over tighten! Wait a few minutes and slowly and carefully turn the gauge in a counterclockwise direction until it is in a vertical position. If it does not, then one or more valves have been left open; check that they are all closed.
The hoses must be attached to their respective glass pieces before the distillation apparatus is assembled.
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